Guests in wheelchairs may consequently not be able to participate in certain activities or shore excursions in tender ports. To ensure the safety of our guests and crew, wheelchairs may not be used to transfer from the ship to a tender. All wheelchairs and scooters must be stored in your stateroom they cannot be left in the hallway or any other public area. If you do not wish to bring your own wheelchair on board, please contact our U.S.-based supplier Scooteround on 001 (888) 441 7575 to arrange delivery of one to the ship. If you do use a wheelchair, you must bring your own and it must be collapsible. We have a limited number of staterooms per ship that are wheelchair accessible with grab rails in the bathrooms, lower sinks and toilets, shower seats, raised beds, adjustable hanging rods in wardrobes, tilting mirrors and extra wide doors for easy access. Unless and until specifically confirmed as accepted, all special requests and requirements are subject to availability and do not form part of the contracted services. Any special requirements which we have accepted will be specifically confirmed as accepted on your confirmation invoice. Any assistance provided by Norwegian Cruise Line, its team members or service providers does not form part of the contracted services unless agreed differently in writing or where required by legal regulations (for example, in accordance with EU regulation 1107/2006 dated 5 July 2006 on the rights of disabled persons and persons with reduced mobility when travelling by air and EU regulation 1177/2010 dated 24 November 2010 concerning the rights of passengers when travelling by sea). Guests who have significant mobility impairments should travel with someone who will take responsibility for any assistance needed during the cruise and in the event of an emergency. If you suffer from reduced mobility or any medical condition or disability which may affect your holiday, please give us full details before booking so that we can provide you with precise information as to the suitability of the holiday taking into account your specific needs. However, reduced mobility of course means different things to different individuals as we fully appreciate that individual capabilities, restrictions and requirements will vary considerably. The information you are provided with about your holiday (which may be on our website, in our brochures or elsewhere) before you make your booking will include a general indication of the suitability of the holiday for someone with reduced mobility. If it is followed by a letter it is a standard cabin with A being the most desired location.Īs example a Mini Suite MA is in a more desired location than a Mini Suite MB.We welcome guests with special needs. If the letter is followed by a number it is a specialty cabin. The primary categories are S=Suite, M=Mini Suites, B=Balconies, O=Oceanview, I=Inside, and T=Studio. Norwegian uses a two digit code for its categories. You will find diagrams, pictures and information about that cabin category including square footage and For detailed information, mouse over a cabin on the deck plans and a pop up window will appear. The detail above shows subcategory color, category name, and subcategory name. The only difference in the subcategories is usually location on the ship. The cruise line separates the different categories (Inside, Oceanview, Balcony) into subcategories.
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I know this doesn't actually answer your question, but I hope that it explains why your question is flawed. This corresponds well to simple overlap between the p orbitals of sulfur with the s orbital of hydrogen. molecular geometries in this domain: Trigonal bipyramidal Seesaw T-shaped Linear. In larger atoms however, we do not always need to invoke hybridization. This is the Valence-Shell Electron-Pair Repulsion (VSEPR) model. seesaw molecular XeCl4 geometry octahedral electron sp geometry BeF2 polar nonpolar, but contains a sp2 polar covalent bond linear : BCI3 trigonal planar sp3. Hybridization needs to be invoked to rationalize the molecular geometries around small atoms (O,N,C, etc) with the geometry of the atomic orbitals in these atoms. Normally, when all these regions are bonding, the molecule has 120 degree angles between the three atoms making up the 'trigonal' part of the shape and 90 degree angles between the two atoms of the 'bipyramidal' part of the shape in relation to the other atoms. One of the problems here is that instructors (and textbooks), especially at an introductory level will have a tendency to over-generalize the rules for Lewis diagrams and for hybridization. For the seesaw shape, we have 5 regions of electron density (trigonal bipyramidal), consisting of 4 bonding pairs and 1 lone pair. As such, the sp 3d and sp 3d 2 hybridizations are incorrect. As others have mentioned, it has been shown that d-orbitals do not participate in hybridization. Sulfur hexafluoride, for example appears to be a covalent-ionic hybrid.Īt the same time, Lewis drawings of hypervalent species such as sulfate ion are still commonly used in organic chemistry, biochemistry and biology. This means that CO2 molecules are non-polar and will not be very soluble in water (a polar solvent). For example, carbon dioxide is a linear molecule. Explanation: The shape of a molecule helps to determine its properties. Seesaw geometry is a form of molecular geometry in which the central atom has one lone pair of electrons and is coupled to four bonding groups. This Wikipedia article does a reasonably good job at looking at the issue: hypervalent molecule.īasically, the even though we can draw Lewis structures of hypervalent compounds, it doesn't mean that they exist as such. Answer: Molecular geometry is used to determine the shapes of molecules. For example, if we want to obtain the Lewis structure of the Sulfate ion. Hypervalency (expanded octets) don't appear to actually exist. It forms a see-saw shape and has a trigonal bipyramidal molecular geometry. The valence shell electron pair repulsion (VSEPR) model focuses on the bonding and nonbonding electron pairs present in the outermost (valence) shell of an atom that connects with two or more other atoms.įundamentally, the VSEPR model theorizes that these regions of negative electric charge will repel each other, causing them (and the chemical bonds that they form) to stay as far apart as possible.This is a complicated issue, and there are many problems with what you are asking. one electron pair include the pair PdH,- and ClF3, which are T-shaped, and RhB, and SF, which both adopt seesaw geometries.
The rest is nearly identical to last year's "best overall iPhone", the iPhone 13 Pro Max. Review: Apple iPhone 14 Pro and 14 Pro Maxīattery life and general performance get a bump, too, with the iPhone 14 Pro Max proving its endurance during ZDNET's testing period. That includes "Dynamic Island," which replaces the iconic notch with a pill that doubles as a live status indicator, eSIM, A16 Bionic chip, and a new 48MP main sensor that shoots some of the most detailed imagery that our reviewers have ever seen on an iPhone. The 6.7-inch model is the largest of the iPhone 14 line and comes stacked with the latest features that Apple has to offer. This year's best overall iPhone currently goes to the iPhone 14 Pro Max. Tech specs: Processor: Apple A16 | Display size: 6.7 inches | Storage options: 128GB/256GB/512GB/1TB | Rear cameras: 48MP wide, 12MP ultra-wide, and 12MP telephoto | Front camera: 12MP f/1.9 | Colors: Silver, Space Black, Gold, Deep Purple | Size: 160.7 x 77.7 x 7.85mm | Weight: 240 g | Starting price: $1,099 If you see inaccuracies in our content, please report the mistake via this form. If we have made an error or published misleading information, we will correct or clarify the article. Our editors thoroughly review and fact-check every article to ensure that our content meets the highest standards. Our goal is to deliver the most accurate information and the most knowledgeable advice possible in order to help you make smarter buying decisions on tech gear and a wide array of products and services. ZDNET's editorial team writes on behalf of you, our reader. Indeed, we follow strict guidelines that ensure our editorial content is never influenced by advertisers. Neither ZDNET nor the author are compensated for these independent reviews. This helps support our work, but does not affect what we cover or how, and it does not affect the price you pay. When you click through from our site to a retailer and buy a product or service, we may earn affiliate commissions. And we pore over customer reviews to find out what matters to real people who already own and use the products and services we’re assessing. We gather data from the best available sources, including vendor and retailer listings as well as other relevant and independent reviews sites. ZDNET's recommendations are based on many hours of testing, research, and comparison shopping. You Can Also Purchase SnapCut Auto Photo Cutting Software. As no active threats were reported recently by users, is SAFE to browse. Picasso 3D FlipBook Video Maker is the most useful and powerful software especially for making 3d flipbooks of your client’s wedding photo album designs quickly. 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Windows Movie Maker is an excellent editing software for making animated movies, and it's quite easy to use with its user-friendly interface. It will allow you to make your own original animation films that can be sent as attachments to Microsoft Word documents and stored onto hard drives. It is designed to closely copy the conventional 2D animated film process, much like the popular Toon Boom Harmony and TVPaint. Super flipbook software Viewable on Windows, Mac & Linux iPad, iPhone, Android & Kindle. DigiCel FlipBook Video is a 2D animated video software that runs on Microsoft Windows PC or Mac OS X perfectly. 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"It's very important to note that even in the winter or on cloudy days, blocking UV rays is still important because they penetrate clouds," she adds. Esther Young, Director of Optometry at EyeQue. "Just like sunscreen lotion, sunglasses block harmful UV rays which can cause and accelerate a number of conditions in and around the eyes," says Dr. (Look for labels that say "100 percent UV protection" or "UV absorption up to 400 nanometers. Beyond that, shades should also be comfortable and offer maximum protection. Leigh Plowman, Optometrist and Dry Eye Directory founder, recommends seeking out shades with polarized lenses that help reduce glare and eye strain. There are a couple of things to look for when choosing the right pair. Instead, invest in the right pair of sunglasses for your needs and adventures. Even if you have the right shoes, jacket, and the most comfortable pack, skimping on sunglasses can make for a long day of squinting followed by an inevitable headache. If this occurs, there may be debris in the mechanism. BMW issued service bulletin SI B65 03 19 in January 2019, which advised that “the iDrive controller knob sticks to the left after regular actuation.” The iDrive Knob Selects The Wrong ItemsĪnother possible problem is that the iDrive knob randomly selects some items at times and other items it won’t select. You should also be aware that iDrive Controller failure is a known fault in certain units which suffer an internal break. Here is a great video on iDrive Controller removal and repair. You don’t need to be an expert at soldering to complete this, but if you do not feel comfortable you can purchase a replacement iDrive Controller for under $200. Once you have the iDrive Controller removed, the most common issue is that the important connecting points need to be re-soldered. You will need a plastic pry tool, a rachet, and a set of small metric sockets. The good news here is that the iDrive Controller is straightforward to remove. Possible Solution: Remove the iDrive Controller and check for any damage to the motherboard. If the iDrive knob becomes sticky and difficult to turn, it may be because a sugary drink has been spilled on it or the connections on the iDrive motherboard are bad. The iDrive Knob Becomes Sticky Or Tough To Turn This is one of the most common issues with iDrive controllers, as by its very nature of being installed in the center of the vehicle it is vulnerable to all kinds of drinks and debris getting into the controller. The circular control device develops a fault. The iDrive computer (named the navigation) which controls the system.The round iDrive controller unit installed between the two front seats.What To Do If The iDrive Controller Is Not Working?Īs explained later in this article, the term “iDrive Controller” often refers to one of two devices. If you are a BMW DIY owner, check out my list of most recommended tools and equipment for BMW maintenance. It is the heart of the system, and if there is a fault, it probably is within this unit. The iDrive computer is generally referred to as the “navigation” and this article will use this term even though it provides much greater functionality than merely the navigation function. If the button or iDrive controller unit is defective, cleaning or re-soldering the motherboard pins may fix it however, it will need to be professionally repaired if the computer is defective. If the BMW iDrive controller is not working, it may be a faulty iDrive circular dial or the central iDrive control computer is defective. That being said, the Drive system utilizes a lot of electronic components and things do go wrong from time to time. Over the years, however, it has grown into a slick central control that places all of the BMW cabin functions into a single system. When iDrive was first launched by BMW in the 2001 7 Series, it received a mixed reaction as the early systems were slow and cumbersome and involved the driver taking eyes off the road to manipulate the control. XP's Windows Firewall cannot block outbound connections it is only capable of blocking inbound ones. A number of additions were made to Group Policy, so that Windows system administrators could configure the Windows Firewall product on a company-wide level. It also fixed a problem whereby the firewall policies would not be enabled on a network connection until several seconds after the connection itself was created, thereby creating a window of vulnerability. Every type of network connection, whether it is wired, wireless, VPN, or even FireWire, has the firewall enabled by default, with some built-in exceptions to allow connections from machines on the local network. Windows Firewall was first introduced as part of Windows XP Service Pack 2. Windows Firewall settings in Windows XP Service Pack 2. It is similar to the one found in Windows XP. In the unreleased Windows Neptune, the firewall was introduced. All features are available regardless of how it is configured. Windows Firewall can be controlled/configured through a COM object-oriented API, scriptable through the netsh command, through the GUI administration tool or centrally through group policies. This security log is not enabled by default the administrator must enable it. This can be used, for instance, to track every time a computer on the network connects to a website. It can record both dropped packets and successful connections. Security log capabilities are included, which can record IP addresses and other data relating to connections originating from the home or office network or the Internet. The domain profile is selected automatically when connected to a network with a domain trusted by the local computer. It allows more inbound connections to allow for file sharing etc. Domain profile is the least restrictive.A network is never assumed to be private unless designated as such by a local administrator. Private assumes that the network is isolated from the Internet and allows more inbound connections than public.Public assumes that the network is shared with the World and is the most restrictive profile.One of three profiles is activated automatically for each network interface: Because of these incidents, as well as other criticisms that Microsoft was not being active in protecting customers from threats, Microsoft decided to significantly improve both the functionality and the interface of Windows XP's built-in firewall, rebrand it as Windows Firewall, and switched it on by default since Windows XP SP2. The ongoing prevalence of these worms through 2004 resulted in unpatched machines being infected within a matter of minutes. Several months later, the Sasser worm did something similar. In mid-2003, the Blaster worm attacked a large number of Windows machines, taking advantage of flaws in the RPC Windows service. It was disabled by default due to concerns with backward compatibility, and the configuration screens were buried away in network configuration screens that many users never looked at. When Windows XP was originally shipped in October 2001, it included a limited firewall called "Internet Connection Firewall". Before the release of Windows XP Service Pack 2, it was known as the " Internet Connection Firewall." It was first included in Windows XP SP2 and Windows Server 2003 SP1. Windows Firewall (officially called Microsoft Defender Firewall in Windows 10 version 2004 and later) is a firewall component of Microsoft Windows. A little bit of cleaning each day – working through the house one room at a time.Every household is different when it come to creating a cleaning schedule, here are two approaches that you might take: Cleaning away dirt, germs and dusts will help reduce allergies and kill bacteria. It saves time – Planning meals and doing one big grocery shop for the week eliminates the need to have to drop into the grocery store every day or two to pick up food for dinner, which then usually results in buying other food which you may not need.Ĭhristie has many great family friendly recipes which can be found here that will help with your weekly meal planning.Ī clean house isn’t just nice to have, it is essential for your health.Also, if I happen to be out late with the kids, hubby can look on the planner and make dinner… no excuses why he can’t!! It saves my sanity – 5pm on a busy weekday evening I don’t have to wonder what to cook the family, I have it already planned, with groceries stocked in the fridge and all I need to do is make it.There are many benefits of meal planning, here are my favourite two: It is one of the key elements that keeps me sane in the evening. I create a meal plan each week either the night before or morning I go grocery shopping. Mostly I love giving the kids their own morning routine as it prevents me from yelling at them to hurry up, have you brushed your teeth, put your shoes on, etc. Having a routine will take the stress out of a hectic morning, as you already know what you need to do. I find this especially on school mornings – making school lunches, getting kids dressed, doing hair, packing bags, cleaning kitchen, putting washing on the line, getting yourself dressed… and everything else!! Creating a routine for yourself and the kids will help ensure that all the tasks you want done get done. Many mums experience a feeling of groundhog day. The Organised Housewife’s Top 5 Organising Tips & Tricks For a Happier Home I hope these tips will help you organise your home so that you and your family can enjoy the space around you. Today I want to share with you some of the organising tips and tricks that have helped me to create a happier, more organised home. Being that I had two little babies to care for there came a point that I knew something had to change, for my own sanity I had to gain back control and change my mindset (you can read more of my story here). Having my twins all those years ago I struggled to keep my home clean and organised. Today I welcome Katrina Springer from The Organised Housewife with 5 fabulous suggestions for getting your home (and life!) organised. Sevierville is centered on the stretch of land between these two junctions of the East and Middle Fork and the West Fork, known traditionally as Forks-of-the-Pigeon or Forks-of-the-River. Five miles (8 km) downstream to the west, the Little Pigeon absorbs its West Fork before turning north and flowing for another five miles (8 km) to its mouth along the French Broad River. In the town's eastern section, the Little Pigeon River is formed by the confluence of its East Fork and Middle Fork, both of which flow down from their sources high in the Great Smoky Mountains. To the east, the Forbidden Caverns are vast underground caves with calcite formations. The Tennessee Museum of Aviation has vintage aircraft, including 2 rare P-47 Thunderbolts. A statue of country singer Dolly Parton, a Sevierville native, is downtown by the 1896 beaux arts–style courthouse. To the south, Great Smoky Mountains National Park has forest trails and waterfalls. Thanks for stopping by our site, we hope to earn your business. If you don’t see what you’re looking for, let us know and we’ll do our best to find it for you.Īnd of course, if you have a special car or a barn find yourself, we would love to take a look at it. We are a premier classic car company that will showcase ony the most interesting cars available. We will post all kinds of videos here about all of those types of cars. His collection began in 1975 with a black 1970 Chevelle and has grown since.Įxperience one of the largest & most incredible collection of American Made Cars in the nation! See 90 cars worth over $8 million! You will also enjoy the 50's, 60's and early 70's Cars of Distinction, Beauty, and Style! We also feature over 5,000 museum treasures, plus a comfortable 6,000 square foot gift shop where you can chose from over 18,000 collectibles, unique gift items, memorabilia, T-shirts, die casts, posters.and more! If it has muscle we have it waiting for you! Floyd began finding and buying the vintage muscle cars he remembered from his youth - focusing on the rare and unusual. Floyd hails from Fernandina Beach Florida. With over 40 years of hands on experience and a friendly smile, he can answer just about any question you have when it comes to Muscle Cars. Nationally known muscle car expert, Floyd Garrett is considered an authority in 60's and 70's high performance automobiles. Bobby Chestnut Interviews Floyd Garrett At The Muscle Car Museum in Tennessee.ĬORVETTES MUSTANGS BARN FINDS CLASSIC CARS MUSCLE If a human is stung, that area will swell and they’ll experience a lot of pain – pain so bad that even morphine won’t relieve it. In captivity, where a platypus can’t escape attacks as easily, this can be deadly. The platypus wraps its hind legs around its victim, driving in its sharp spurs, and releases venom, temporarily paralyzing another male platypus in the wild. Male platypuses make more venom during the breeding season, which researchers think helps them defend their territory and compete for females. And you’ll only find these spurs on males. Yep, a spur – it kinda looks like a really scary claw. These cuties found here have venom that can be lethal, but there are no recorded cases of them killing humans.ĭuck-billed platypi have venom glands connected to a spur on each of their hind legs. The duck-billed platypus is another venom-producing mammal, but doesn’t get much attention because you probably won’t ever see one. And that adaptation seems to also be the case for a bunch of other tetrodotoxin-harboring creatures. It actually isn’t a problem – researchers have found that its own sodium channels have amino acid changes that most likely prevent tetrodotoxin from binding, which protects the octopus. Sounds kinda dangerous for the blue-ringed octopus itself, right? Many researchers believe that bacteria living in octopuses’ salivary glands produce the toxin. What’s interesting about the greater blue-ringed octopus’s tetrodotoxin is that the octopus isn’t making it itself. Victims who live through the first 24 hours often make a complete recovery. Unfortunately, there is no antitoxin, so the standard treatment is to hook a victim up to a ventilator and monitor their heart rate until the toxin naturally makes its way out of their system. Maybe the eeriest part of the whole thing is that a victim can be fully aware of their surroundings but unable to breathe or signal that they can’t breathe – because they’re paralyzed. When tetrodotoxin binds to a sodium channel it prevents sodium ions from moving through the channel, which stops nerve cells from sending chemical messages to your brain like “body, move!” and “heart, keep pumping blood!” First, this will cause numbness around the bite, then paralysis, then heart failure. Tetrodotoxin works by blocking the activity of sodium channels in your nerve cells. Its molecule of death is tetrodotoxin, a potent nerve toxin, found in this cute little octopus’s salivary glands, which are connected to its beak. can deliver a bite that’s fatal to humans… although it happens VERY rarely. This greater blue-ringed octopus, found here. That’s a puzzle scientists are trying to solve. That could be because of chemicals from the sexual gland alone, or because those chemicals mix, or react with others in slow loris saliva. One of these compounds is very similar to the allergen in cat dander, but way more powerful. It appears to be a chemical concoction of over 200 compounds. Slow loris sexual gland secretion isn’t very well understood. You might feel like you’re suffocating.Ī big shot of adrenaline, like from an EpiPen, can be used to stop that scary allergic response, but EpiPens just keep you alive in that moment-you need to go to the ER immediately because chances are, once the adrenaline wears off, you could go into anaphylactic shock again. In other words, your immune system, when reacting to the toxins, releases a bunch of chemicals that make your blood pressure drop suddenly and cause your airways to narrow. The bite of a slow loris can kill you by giving you a terrible allergy attack, throwing you into anaphylactic shock. When slow lorises groom themselves, they lick that gland, so if they happen to bite you, those toxins will come with their saliva… which could be toxic on its own. Scientists believe that this sexual gland secretion could also be helpful for keeping parasites at bay, as well as predators who can smell it. MUSIC: This slow loris, is gonna take it slow. Toxins from one Indonesian species of slow loris come from a gland on the surface of the slow loris’ arm that they use to chemically communicate with potential mates. Very few mammals are known to be venomous-the slow loris is one of them. One of these five adorable animals might be the last thing you ever see. r/Pokemon Discord discord.If looks could kill, at least these are really cute looks. R/pokemon is the place for most things Pokémon on Reddit-TV shows, video games, toys, trading cards, you name it! |
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